Recent Papers of LUMILA group (Back to LUMILA Home Page)
Ernesto Brunet, Marıia Jose de la Mata, Hussein M. H. Alhendawi, Carlos Cerro, Marina Alonso, Olga Juanes, and Juan Carlos Rodriguez-Ubis
Engineering of Microcrystaline Solid-State Networks Using Cross-Linked ç-Zirconium Phosphate/Hypophosphite with Nonrigid Polyethylenoxadiphosphonates. Easy Access to Porously Dynamic Solids with Polar/Nonpolar Pores. Chem. Mater. (2005), 17, 1424-1433


Brunet, Ernesto; De la Mata, Maria; Juanes, Olga; Rodriguez-Ubis, Juan Carlos.  Sensitized Luminescence of Lanthanides within the Walls of Polyethylenoxa-Pillared g-Zirconium Phosphate. Chemistry of Materials  (2004),  16(8),  1517-1522.

Lantano, Beatriz; Aguirre, Jose M.; Finkielsztein, Liliana; Alesso, Elba N.; Brunet, Ernesto; Moltrasio, Graciela Y.  A formal [3 + 2] alkene addition to benzhydrol cations. A practical and mild methodology for the synthesis of substituted 1-arylindanes and related compounds.    Synthetic Communications  (2004),  34(4),  625-641

Brunet, Ernesto; de la Mata, Maria Jose; Juanes, Olga; Rodriguez-Ubis, Juan Carlos.  Solid-state reshaping of crystals: Flash increase in porosity of zirconium phosphate-hypophosphite that contains polyethylenoxa diphosphonate pillars.    Angewandte Chemie, International Edition  (2004),  43(5),  619-621.

Alesso, Elba; Torviso, Rosario; Lantano, Beatriz; Erlich, Magali; Finkielsztein, Liliana M.; Moltrasio, Graciela; Aguirre, Jose M.; Brunet, Ernesto.  Synthesis of 1-ethyl-2-methyl-3-arylindanes.Stereochemistry of five-membered ring formation. ARKIVOC (2003),   (10),  283-297

Ernesto Brunet, Marina Alonso, María José de la Mata, Sylvie Fernández, Olga Juanes, Olivier Chavanes, and Juan-Carlos Rodríguez-Ubis. Covalent Bonding of Phosphonates of Fullerene and Ru Complexes to g-Zirconium Phosphate as a Template for Building Chemical Devices in the Solid State.Chemistry of Materials (2003), 15(6), 1232-1234
Brunet, Ernesto; Juanes, Olga; Sedano, Rosa; Rodriguez-Ubis, Juan-Carlos. Lanthanide Complexes of Polycarboxylate-bearing Dipyrazolylpyridine Ligands with Near Unity Luminescence Quantum Yields: the Effect of Pyridine Substitution    Photochemical and Photobiological Sciences  (2002),  1, 613-618.
Galoup, Chantal; Azéma, Joëlle; Tisnès, Pierre; Picard, Claude; Ramos, Patricia; Juanes, Olga; Brunet, Ernesto; Rodriguez-Ubis, Juan Carlos. Luminescence of Eu3+ and Tb3+ complexes of two macrobicyclic ligands derived from a tetralactam ring and a chromophoric antenna.    Helvetica Chimica Acta  (2002),  85,  1613-1625.
Noguera, Patricia; Maquieira, Angel; Puchades, Rosa; Brunet, Ernesto; Carramolino, M. Mar; Rodriguez-Ubis, Juan Carlos. Development of an enzyme-linked immunosorbent assay for pentachlorophenol.    Analytica Chimica Acta  (2002),  460(2),  279-288.
Noguera, Patricia; Maquieira, Angel; Puchades, Rosa; Brunet, Ernesto; Carramolino, Ma Mar; Rodriguez-Ubis, Juan Carlos. Development of an enzyme-linked immunosorbent assay for screening contamination by chlorophenols in environmental waters.    Journal of Environmental Monitoring  (2002),  4(3),  442-448.
Brunet, Ernesto; Garcia-Losada, Pablo; Rodriguez-Ubis, Juan-Carlos; Juanes, Olga. Synthesis of new fluorophores derived from monoazacrown ethers and coumarin nucleus.    Canadian Journal of Chemistry  (2002),  80(2),  169-174.
Alonso, Maria-Teresa; Brunet, Ernesto; Juanes, Olga; Rodriguez-Ubis, Juan-Carlos. Synthesis and photochemical properties of new coumarin-derived ionophores and their alkaline-earth and lanthanide complexes.    Journal of Photochemistry and Photobiology, A: Chemistry  (2002),  147(2),  113-125.
Brunet, Ernesto.  Asymmetric induction under confinement.    Chirality  (2002),  14(2/3),  135-143.
Blanco, M. Aranzazu; Lopez-Torres, Elena; Mendiola, M. Antonia; Brunet, Ernesto; Sevilla, M. Teresa. Macrocyclization of cyclic thiosemicarbazones with mercury salts.    Tetrahedron  (2002),  58(8),  1525-1531.
Brunet, Ernesto; Juanes, Olga; Sedano, Rosa; Rodriguez-Ubis, Juan-Carlos. Synthesis of Novel Macrocyclic Lanthanide Chelates Derived from Bis-pyrazolylpyridine.    Organic Letters  (2002),  4(2),  213-216.
Brunet, Ernesto; Alonso, Maria Teresa; Juanes, Olga; Velasco, Óscar; Rodriguez-Ubis, Juan C. Novel Polyaminocarboxylate chelates derived from 3-aroylcoumarins.Tetrahedron (2001), 57, 3105-3116.
Rodriguez-Ubis, Juan C.; Alonso, Maria Teresa; Juanes, Olga; Brunet, Ernesto. Luminescent cryptands. 3-aroylcoumarin macrobicyclic complexes of europium(III) and terbium(III): the effect of coumarin substitution.    Luminescence  (2000),  15(6),  331-340.
 
Brunet, Ernesto; Juanes, Olga; De la Mata, Maria Jose; Rodriguez-Ubis, Juan C. A simple polyheterotopic molecular receptor derived from bispyrazolylmethane showing ambivalent allosteric cooperation of zinc(II).    European Journal of Organic Chemistry  (2000),   (10),  1913-1922.
 
Azema, Joelle; Galaup, Chantal; Picard, Claude; Tisnes, Pierre; Ramos, Patricia; Juanes, Olga; Rodriguez-Ubis, Juan Carlos; Brunet, Ernesto. New macrobicycles containing a tetralactam moiety: template synthesis and study of their binding with lanthanides.    Tetrahedron  (2000),  56(17),  2673-2681.
 
Juanes, Olga; Rodriguez-Ubis, Juan Carlos; Brunet, Ernesto; Pennemann, Helmut; Kossenjans, Michael; Martens, Jurgen.  New chiral catalysts containing N,O-heterocycles derived from chiral amino alcohols.    European Journal of Organic Chemistry  (1999),   (12),  3323-3333.
 
Alberti, Giulio; Brunet, Ernesto; Dionigi, Chiara; Juanes, Olga; De la Mata, Maria Jose; Rodriguez-Ubis, Juan Carlos; Vivani, Riccardo. Shaping solid-state supramolecular cavities: chemically induced accordion-like movement of g-zirconium phosphate containing polyethylenoxide pillars.    Angewandte Chemie, International Edition  (1999),  38(22),  3351-3353.
 
Kossenjans, Michael; Pennemann, Helmut; Martens, Jurgen; Juanes, Olga; Rodriguez-Ubis, Juan C.; Brunet, Ernesto.  New N,O-heterocycles derived from (R)-cysteine as catalysts in the enantioselective diethylzinc addition.    Tetrahedron: Asymmetry  (1998),  9(23),  4123-4125.
 
Rodriguez-Ubis, Juan C.; Alonso, Maria T.; Juanes, Olga; Sedano, Rosa; Brunet, Ernesto. The discovery of a simple ligand based on acetophenone bearing excellent quantum yields for the excitation of Eu3+ and Tb3+.    Journal of Luminescence  (1998),  79(2),  121-125.
 
Brunet, Ernesto; Alonso, Maria T.; Juanes, Olga; Sedano, Rosa; Rodriguez-Ubis, Juan C. Unusual behavior of 7-diethylamino-3-(3,4-ethylendioxybenzoyl)coumarin towards group IIA cations: a potential photoactive probe for magnesium.    Tetrahedron Letters  (1997),  38(25),  4459-4462.
 
Takalo, Harri; Mukkala, Veli Matti; Merio, Liisa; Rodriguez-Ubis, Juan Carlos; Sedano, Rosa; Juanes, Olga; Brunet, Ernesto. Development of luminescent terbium(III) chelates for protein labeling. Effect of triplet-state energy level.    Helvetica Chimica Acta  (1997),  80(2),  372-387. 
 
Rodriguez-Ubis, Juan Carlos; Sedano, Rosa; Barroso, Gemma; Juanes, Olga; Brunet, Ernesto. Lanthanide complexes of polyacid ligands derived from 2,6-bis(pyrazol-1-yl)pyridine, -pyrazine, and 6,6'-bis(pyrazol-1-yl)-2,2'-bipyridine. Synthesis and luminescence properties.    Helvetica Chimica Acta  (1997),  80(1),  86-96.
 
Brunet, Ernesto; Huelva, Manuel; Vazquez, Raquel; Juanes, Olga; Rodriguez-Ubis, Juan C. Covalent bonding of crown ethers to g-zirconium phosphate - new layered ion exchangers showing selective recognition.    Chemistry--A European Journal  (1996),  2(12),  1578-1584.
 
Brunet, Ernesto; Huelva, Manuel; Rodriguez-Ubis, Juan C. Covalent bonding of aza-18-crown-6 to g-zirconium phosphate. A new layered ion-exchanger with potential recognition capabilities.    Tetrahedron Lett.  (1994),  35(46),  8697-700.
 
Rodriguez-Ubis, Juan Carlos; Alonso, Maria Teresa; Brunet, Ernesto.  Synthesis and luminescence properties of europium(III) and terbium(III) complexes of aminopolycarboxylic acid ligands containing 3-aroylcoumarin.    Tetrahedron Lett.  (1994),  35(45),  8461-4.
 
Batra, Manohar Singh; Aguilar, Francisco J.; Brunet, Ernesto. On the diastereoselectivity of cyanide addition to b-hydroxy ketones: one-pot synthesis of syn b-hydroxy cyanohydrins and anti 2,4-dihydroxy amides.Tetrahedron  (1994),  50(27),  8169-84.
 
Brunet, Ernesto; Poveda, Ana M.; Rabasco, Dolores; Oreja, Enrique; Font, Luis M.; BAtra, Manohar Singh; Rodriguez-Ubis, Juan C. New chiral crown ethers derived from camphor and their application to asymmetric Michael addition. First attempts to rationalize enantioselection by AM1 and AMBER calculations.    Tetrahedron:  Asymmetry  (1994),  5(5),  935-48.
 
Martinez-Jimeno, Miguel A.; Brunet, Ernesto; Sieiro, Carlos. EPR spectrum simulator.    J. Chem. Educ.:  Software, Ser. B  (1993),  6B(1),  15-17, 26-9.
 
Rodriguez-Ubis, Juan C.; Juanes, Olga; Brunet, Ernesto. A simple polyheterotopic molecular receptor derived from bispyrazolylmethane showing negative allosteric cooperation of Zn(II).    Tetrahedron Lett.  (1994),  35(8),  1295-8.
 
Alonso, Maria Teresa; Brunet, Ernesto; Hernandez, Concepcion; Rodriguez-Ubis, Juan Carlos. Synthesis and complexation properties of 3-aroylcoumarin crown ethers. A new class of photoactive macrocycles.    Tetrahedron Lett.  (1993),  34(46),  7465-8.
 
Gallego, Maria Teresa; Brunet, Ernesto; Garcia Ruano, Jose Luis; Eliel, Ernest L. Conformational analysis of methylthiazanes: the problem of the methyl-carbon-nitrogen-methyl gauche interaction.    J. Org. Chem.  (1993),  58(15),  3905-11.
 
Batra, Manohar; Brunet, Ernesto.  The diastereoselective preparation of syn-b-hydroxycyanohydrins by addition of cyanide to b-hydroxy ketones with dimethyldicyanosilane.    Tetrahedron Lett.  (1993),  34(4),  711-14.
 
Brunet, Ernesto; Batra, Manohar Singh; Aguilar, Francisco J.; Garcia Ruano, Jose Luis. Highly diastereoselective addition of cyanide to b-hydroxy ketones.    Tetrahedron Lett.  (1991),  32(39),  5423-4.
 
Gallego, Maria Teresa; Brunet, Ernesto; Garcia Ruano, Lose Luis; Eliel, Ernest L. Diastereospecific synthesis of cis- and trans-2,3-dimethyl-1,4-thiamorpholines:  an advanced organic synthesis and NMR project.    J. Chem. Educ.  (1991),  68(6),  517-20. 
 
Eliel, Ernest L.; Brunet, Ernesto. Quantitative relationship between optical rotation and conformation.    J. Org. Chem.  (1991),  56(4),  1668-70.
 
Brunet, Ernesto; Azpeitia, Paloma. Conformational analysis of 3-aminothiacyclohexane and derivatives by low-temperature carbon-13 NMR.Tetrahedron  (1988),  44(6),  1751-62.
 
Brunet, Ernesto; Gallego, Maria Teresa; Garcia Ruano, Jose Luis; Parellada, Dolores; Rodriguez, Jesus H.; Urbano, Antonio. Stereospecific synthesis of 2,3-dimethyl-1,4-thiamorpholines by cyclization of b-N-methoxycarbonylaminoalkyl vinyl sulfoxides and related compounds.    Tetrahedron  (1988),  44(5),  1421-30.
 
Eliel, Ernest L.; Brunet, Ernesto.  Energies of the stilbenes and stilbene dibromides.    J. Org. Chem.  (1986),  51(10),  1902-4.
 
Brunet, Ernesto; Eliel, Ernest L.; Kenan, W. R., Jr.  Conformational analysis. 46.  Conformational equilibria in 3-hydroxy-, 3-methoxy-, and 3-acetoxythianes, their sulfoxides and sulfones, and some corresponding 3-methyl homologs.    J. Org. Chem.  (1986),  51(5),  677-86.
 
Eliel, Ernest L.; Brunet, Ernesto. Large concentration effects on conformational equilibria.    Tetrahedron Lett.  (1985),  26(29),  3421-2.