Selected Publications
1. Synthesis of 1,4-Diketones by Palladium-Catalyzed reductive Coupling of
Acid Chlorides with (E)-1,2-Bis(tri-n-butylstannyl)ethene or b-Stannnyl Enones.
Pérez,
M.; Castaño, A. M.; Echavarren, A. M.
J. Org. Chem. 1992, 57, 5047 - 5049.
2. Strategies for the Synthesis of Palladium Enolates and Homoenolates:
Palladation of Ketone N,N-Dimethylhydrazones.
Cárdenas,
D. J.; Echavarren, A. M.
Anales de Química 1993, 89, 107-110.
3. Synthesis of Ru(II) Hydride and Alkenyl Amidine Complexes. The Crystal
Structure of [Ru(CO)(CH=CHCMe3){NH=C(Me)(Me2pz)}(PPh3)2]PF6.
López,
J.; Santos, A.; Romero, A.; Echavarren, A. M.
J. Organomet. Chem. 1993, 443, 221 - 228.
4. Synthesis of Butenynylruthenium Complexes from Hydrido, Alkenyl or
Alkynyl Complexes.
Santos,
A.; López, J.; Matas, L.; Ros, J.; Galán, A.; Echavarren, A. M.
Organometallics 1993, 12, 4215 - 4218.
5. Synthesis of Protected 3-Methylaspartic Acids from Glutamic Anhydride
via Nickelacycles.
Castaño,
A,. M.; Echavarren, A. M.
Tetrahedron Lett. 1993, 34, 4361 - 4362.
6. Synthesis of the Benzo[b]carbazoloquinone
with the Structure Proposed for Prekinamycin.
Echavarren,
A. M.; Tamayo, N.; Paredes, M. C.
Tetrahedron Lett. 1993, 34, 4713 - 4716.
7. Aliphatic Palladation of Ketone N,N-Dimethylhydrazones.
Cárdenas,
D. J.; Echavarren, A. M.; Vegas, A.
Organometallics 1994, 13, 882 - 889.
8. Reactivity of a Nickelacycle Derived from Aspartic Acid: Alkylations,
Insertions, and Oxidations.
Castaño,
A. M.; Echavarren, A. M.
Organometallics 1994, 13, 2262 - 2268.
9. Palladium-Catalyzed Reductive Coupling of Acid Chlorides with b-Stannyl Enones: Synthesis of 1,4-Diketones and Mechanistic Aspects.
Echavarren,
A. M.; Pérez, M.; Castaño, A. M.; Cuerva, J. M.
J. Org. Chem. 1994, 59, 4179 - 4185.
10. Design and Synthetic Applications of New Heterometallacycles.
Echavarren,
A. M.; Cárdenas, D. J.; Castaño, A. M.; Cuerva, J. M.; Mateo, C.
Bull. Soc. Chim. Belg. 1994, 103, 549 - 558.
11. Synthesis of New Ruthenium(II) Carbonyl Hydrido, Alkenyl, and Alkynyl
Complexes with Chelating Diphosphines.
Santos,
A.; López, J.; Montoya, J.; Noheda, P.; Romero, A.; Echavarren, A. M.
Organometallics 1994, 13, 3605 - 3615.
12. Formation of a,b-Unsaturated Carbonyl
Compounds by Palladium-Catalyzed Oxidation of Allylic Alcohols.
Gómez-Bengoa,
E.; Noheda, P.; Echavarren, A. M.
Tetrahedron Lett. 1994, 35, 7097 - 7098.
13. Synthesis of Antibiotics WS5995 A and C and Related Compounds by
Palladium-Catalyzed Coupling of 2-Bromonaphthoquinones with Organostannanes.
Echavarren,
A. M.; Tamayo, N.; Cárdenas, D. J.
J. Org. Chem. 1994, 59, 6075 - 6083.
14. A Concise Synthesis of (±)-Monomorine I by way of a Palladium-Catalyzed
Reductive Coupling.
Castaño,
A. M.; Cuerva, J. M.; Echavarren, A. M.
Tetrahedron Lett. 1994, 35, 7435 - 7438.
15. Synthesis of Oxa- and Azapalladacycles from Organostannanes.
Cárdenas,
D. J.; Mateo, C.; Echavarren, A. M.
Angew. Chem., Int. Ed. Engl. 1994, 33, 2445 – 2447; Angew. Chem.
1994, 106, 2529 - 2531.
16. Synthesis of 3-Methylaspartic Acids by Ring-Contraction of a
Nickelacycle Derived from Glutamic Anhydride.
Echavarren,
A. M.; Castaño, A. M.
Tetrahedron 1995, 51, 2369-2378.
17. Selectivity in the Aliphatic Palladation of Ketone Hydrazones. An
Example of Palladium-Promoted Intramolecular Addition of a N,N-Dimethylhydrazone to an Alkene.
Cárdenas,
D. J.; Echavarren, A. M.
Organometallics 1995, 14, 4427-4430.
18. Calix[4]arene Sulfonates: Palladium-Catalyzed Intermolecular Migration
of Sulfonyl Groups and Isolation of a Calix[4]arene in a Chiral 1,2-Alternate
Conformation.
González,
J. J.; Nieto, P. M.; Prados, P.; Echavarren, A. M.; de Mendoza, J.
J. Org. Chem. 1995, 60, 7419-7423.
19. Palladium-Catalyzed Coupling of Allyl Carbonates with Stannanes.
Castaño,
A. M.; Echavarren, A. M.
Tetrahedron Lett. 1996, 37, 6587-6590.
20. Recent Developments in the Synthesis of Marine Pyridoacridine Alkaloids.
Echavarren,
A. M.
Advances in Nitrogen Heterocycles, Vol. 2, Cap. 5; Moody, C. J. Ed.; JAI Press: Greenwich, 1996.
21. Palladium-Switchable Bisnucleophiles.
Castaño,
A. M.; Ruano, M.; Echavarren, A. M.
Tetrahedron Lett. 1996, 37, 6591-6594.
22. Michael reaction of Stabilized Carbon Nucleophiles Catalyzed by [RuH2(PPh3)4].
Gómez-Bengoa,
E.; Cuerva, J. M.; Mateo, C.; Echavarren. A. M.
J. Am. Chem. Soc. 1996, 118, 8553-8565.
23. Syntheses of Phenanthroviridone, Gilvocarcin BE-12406X2, and
Antibiotic WS 5995B Based on the Palladium and Copper Catalyzed Coupling of
Organostannanes with Bromoquinones.
de
Frutos, Ó.; Echavarren, A. M.
Tetrahedron Lett. 1996, 37, 8953-8956.
24. Isolation of Transmetallation Intermediates in the Stille Cross-Coupling Reaction of Stannanes: Synthesis of Palladacycles, Ligand Substitution, and Insertion Reactions.
Mateo,
C.; Cárdenas, D. J.; Fernández-Rivas, C.; Echavarren, A. M.
Chem. Eur. J. 1996, 2, 1596-1606.
25. Synthesis of Heterocyclic Quinones by Aza-Diels-Alder Reaction of a
4-Stannyl-1-azadiene.
Cuerva,
J. M.; Echavarren, A. M.
Synlett 1997, 173-174.
26. Synthesis of Spiro Polycyclic Aromatic Hydrocarbons by Intramolecular
Palladium-Catalyzed Arylation.
González,
J. J.; García, N.; Gómez-Lor, B.; Echavarren, A. M
J. Org. Chem. 1997, 62, 1286-1291.
27. Cationic Intermediates in the Intramolecular Insertion of Alkenes into (h3-Allyl)palladium(II) Complexes.
Gómez-Bengoa,
E.; Manuel Cuerva, J.; Echavarren, A. M., Martorell, G.
Angew. Chem., Int. Ed. Engl. 1997, 36, 767-769; Angew. Chem.
1997, 109, 795-797.
28. Isolation of the Transmetallation Step in the Hiyama Cross-Coupling of Organosilanes.
Mateo,
C.; Fernández-Rivas, C.; Echavarren, A. M.; Cárdenas, D. J.
Organometallics 1997, 16, 1997-1999.
29. The Effect of N-Donor Ligands on the Reaction of Ruthenium Hydrides with 1-Alkynes.
Santos,
A.; López, J.; Galán, A.; González, J. J.; Tinoco, P.; Echavarren, A. M.
Organometallics 1997, 16, 3482-3488.
30. Palladium-Catalyzed Synthesis of Tetraethynyl and Tetraethenyl Biphenyls: Elongated Tetrahedral Tectons.
Gómez-Lor,
B.; Echavarren, A. M.; Santos, A.
Tetrahedron Lett. 1997, 38, 5347-5350.
31. Palladium-Catalyzed Coupling of Naphthoquinone Triflates with Stannanes. Unprecedented Nucleophilic Aromatic Substitution on a Hydroxynaphthoquinone Triflate.
Echavarren,
A. M.; Frutos, Ó.; Tamayo, N.; Noheda, P.; Calle, P.
J. Org. Chem. 1997, 62, 4524-4527.
32. An Approach to the Synthesis of the Benzo[b]fluorene Core of the Kinamycins by an Arylalkyne-Allene
Cycloaddition.
de
Frutos, Ó.; Echavarren, A. M
Tetrahedron Lett. 1997, 38, 7941-7942.
33. Synthesis of Benzo[b]carbazoloquinones
by Coupling of Organostannanes with Bromoquinones.
Echavarren,
A. M.; Tamayo, N.; de Frutos, Ó.; García, A.
Tetrahedron 1997, 53, 16835-16846.
34. Synthesis of (±)-10-epi-Elemol by a Highly Stereoselective
Intramolecular Coupling of an Allylstannane with an Allyl Acetate.
Cuerva,
J. M.; Gómez-Bengoa, E.; Méndez, M.; Echavarren, A. M.
J. Org. Chem. 1997, 62, 7540-7541.
35. Steric Hindrance Facilitated Synthesis of Enynes and Their
Intramolecular [4+2] Cycloaddition with Alkynes.
González,
J. J.; Francesch, A.; Cárdenas, D. J.; Echavarren, A. M.
J. Org. Chem. 1998, 63, 2845 - 2857.
36. Intramolecular Transmetalation of Arylpalladium(II) and Arylplatinum(II)
Complexes with Silanes and Stannanes.
Mateo,
C.; Fernández-Rivas, C.; Cárdenas, D. J.; Echavarren, A. M.
Organometallics 1998, 17, 3661 - 3669.
37. syn-Trialkylated Truxenes: Building Blocks which Self-Associate by Arene Stacking.
de
Frutos, Ó.; Gómez-Lor, B.; Granier, T.; Monge, M. Á.; Gutiérrez-Puebla, E.;
Echavarren, A. M.
Angew. Chem. Int. Ed. 1999, 38, 204 - 207; Angew. Chem.
1999, 111, 186 - 189.
38. Direct Synthesis of N-Aryl Quinone Imine Acetals and Quinol Imines from Acetals.
Carreño,
M. C.; Cuerva, J. M.; Ribagorda, M.; Echavarren, A. M.
Angew. Chem. Int. Ed. 1999, 38, 1449-1452; Angew. Chem.
1999, 111, 1552 - 1555.
39. Divergent Behavior of Pd(II) and Pt(II) in the Matalation of 1,3-Di(2-pyridyl)benzene.
Cárdenas,
D. J.; Echavarren, A. M.; Ramírez de Arellano, M. C.
Organometallics 1999, 18, 3337 - 3341.
40.
New
Synthesis of Pyridoacridines Based on an Intramolecular Aza-Diels-Alder
Reaction Followed by an Unprecedented Rearrangement.
Cuerva,
J. M.; Cárdenas, D. J.; Echavarren, A. M.
Chem. Commun. 1999, 1721-1722.
41. Intracluster Transmetalation of Cuprates with Stannanes.
Mateo,
C.; Cárdenas, D. J.; Martín-Matute, B.; Echavarren, A. M.
Chem. Commun. 1999, 2205-2206.
42. Synthesis of “Crushed Fullerene” C60H30.
Gómez-Lor,
B. de Frutos, Ó.; Echavarren, A. M.
Chem. Commun. 1999, 2431-2432.
43. Synthesis of Fullerene Fragments.
Echavarren,
A. M.; Gómez-Lor, B.; de Frutos, Ó.
Proc. Electrochem. Soc. (2000), (Fullerenes 2000-Volume 9: Functionalized
Fullerenes), 136-155.
44. Metal-Catalyzed Carbocyclization by the Intramolecular Reaction of Allylsilanes and Allylstannanes with Alkynes.
Fernández-Rivas,
C.; Méndez, M.; Echavarren, A. M.
J. Am. Chem. Soc. 2000, 122, 1221-1222.
45. Palladium-Catalyzed Reaction of a Sterically Constrained Trialkyne: A Dimerization-type reaction with a Surprising Finale.
Granier,
T.; Cárdenas, D. J.; Echavarren, A. M.
Tetrahedron Lett. 2000, 41, 6775-6779.
46. Platinum-catalyzed Hydroxy- and Alkoxycyclization of Enynes.
Méndez,
M.; Muñoz, M. P.; Echavarren, A. M.
J. Am. Chem. Soc. 2000, 122, 11549-11550.
47. Nuevas síntesis de fragmentos de fullerenos.
Echavarren,
A. M.; de Frutos, Ó.; Granier, T. Gómez-Lor, B.
Los Materiales Moleculares en España en el umbral del
siglo XXI.
Vázquez,
P.; Torres, T.; Martín, N., Eds.; UAM Ediciones; 2001, pp. 383-400.
48. Synthesis of Benzo[b]phenanthridines and Related Naturally Occurring 2-Aryl-1,4-Naphthoquinones by the Palladium and Copper Catalyzed Coupling of Organostannanes with Bromoquinones
de
Frutos, Ó.; Atienza, C.; Echavarren, A. M.
Eur. J. Org. Chem. 2001, 163-171
49. Reaction of Vinyl Epoxides with Palladium-Switchable Bisnucleophiles:
Synthesis of Carbocycles.
Castaño,
A. M.; Méndez, M.; Ruano, M.; Echavarren, A. M.
J. Org. Chem. 2001, 66, 589-593.
50. Formation of Benzo[b]fluorenes and the Benzo[a]fluorene Core of the Fluostatins by Cyclization of Diaryldiynones.
Atienza,
C.; Mateo, C.; Frutos, Ó.; Echavarren, A. M.
Org. Lett. 2001, 3, 153-155.
51. Intramolecular C-H Activation by Alkylpalladium(II) Complexes: Insights
into the Mechanism of the Palladium-Catalyzed Arylation Reaction.
Martín-Matute,
B.; Mateo, C.; Cárdenas, D. J.; Echavarren, A. M.
Chem. Eur. J. 2001, 7, 2341-2348.
52. Synthesis of New C3v and C3h truxene Derivatives.
Gómez-Lor,
B. de Frutos, Ó.; Ceballos, P. A.; Granier, T.; Echavarren, A. M.
Eur. J. Org. Chem. 2001, 2107-2114.
53. New Palladacycles with a Pd-O Bond: Synthesis, Structure and Reactions.
Fernández-Rivas,
C.; Cárdenas, D. J.; Monge, Á.; Gutiérrez-Puebla, E.; Echavarren, A. M.
Organometallics 2001, 20, 2998-3006..
54. Palladacycles as Precatalysts in Heck and Cross-Coupling Reactions
Muñoz,
M. P.; Martín-Matute, B.; Fernández-Rivas, C.; Cárdenas, D. J.; Echavarren, A.
M.
Adv. Synt. & Catal. 2001, 343, 338-342.
55. Ruthenium-Capping of Di- and Tetraethynylbiphenyls.
Gómez
Lor, B.; Santos, A.; Ruiz, M.; Echavarren, A. M.
Eur. J. Inorg. Chem., 2001, 2305-2310.
56. Cyclizations of Enynes Catalyzed by PtCl2 or Other Transition
Metal Chlorides: Divergent Reaction Pathways
Méndez, M.; Muñoz, M. P.; Nevado, C.; Cárdenas, D. J.; Echavarren, A. M.
J. Am. Chem. Soc. 2001, 123, 10511-10520.
57. Pt(II)-catalyzed Intramolecular Reaction of Furanes with Alkynes
Martín-Matute, B.; Cárdenas, D. J.; Echavarren, A. M.
Angew. Chem. Int. Ed. 2001, 40, 4754-4757; Angew. Chem. 2001, 113, 4890-4893.
58. New Strategies for the Synthesis of Carbocycles Based on
Transition-Metal Catalyzed Cyclization reactions of Organostannanes and
Organosilanes.
Méndez,
M.; Echavarren, A. M.
Eur. J. Org. Chem., 2002, 15-28.
59. Zipping up ‘the crushed fullerene’ C60H30: C60
by fifteen-fold, consecutive intramolecular H2 losses.
Gómez-Lor,
B.; Koper, C.; Fokkens, R. H.; Vlietstra, E. J.; Cleij T. J.;. Jenneskens, L.
W.; Nibbering, N. M. M., Echavarren, A. M.
Chem. Commun. 2002, 370-371.
60. Synthesis and Self-Association of syn-5,10,15-Trialkylated Truxenes.
de
Frutos, Ó.; Granier, T.; Gómez-Lor, B.; Jiménez-Barbero, J.; Monge, A.;
Gutiérrez-Puebla, E.; Echavarren, A. M.
Chem. Eur. J. 2002, 8, 2879-2890.
61. Intramolecular Michael-type Addition of Azadienes to 1,4-Naphthoquinones
instead of Aza-Diels-Alder Cycloaddition: A Synthesis of Ascididemin.
Cuerva,
J. M.; Cárdenas, D. J.; Echavarren,
A. M.
J. Chem. Soc., Perkin Trans. 1 2002, 1360-1365.
62. Intramolecular Coupling of Allyl Carboxylates with Allylstannanes and
Allylsilanes: A New Type of Reductive Elimination Reaction?
Méndez,
M.; Cuerva, J. M.; Gómez-Bengoa, E.; Cárdenas, D. J.; Echavarren, A. M.
Chem. Eur. J. 2002, 8, in press.
63. Reaction of Allylsilanes and Allylstannanes with Alkynes Catalyzed by
Electrophilic Late Transition Metal Chlorides?
Fernández-Rivas,
C.; Méndez, M.; Nieto-Oberhuber, C.; Echavarren A. M.
J. Org. Chem. 2002,
67, in press (jo025812n).
64. Palladium-Catalyzed Intramolecular Arylation Reaction: Mechanism and
Application for the Synthesis of Polyarenes
Echavarren
A. M.; Gómez-Lor, B.; González, J. J.; Frutos, Ó. de
Synlett 2002, in press.