Artículos

2011-

• J. Losada, P. García-Armada, V. Robles, Á. M. Martínez, C.M. Casado, B. Alonso, "Carbosilane based dendritic cores functionalized with interacting ferrocenyl units: synthesis and electrocatalytical properties." New J. Chem., DOI:10.1039/C1NJ20190E.
• A. Nievas, J. J. González, E. Hernández, E. Delgado, A. Martín, C. M. Casado, B. Alonso "Hydrosilylation of Ferrocenylalkyne–dicobalthexacarbonyl complexes. Model Reactions for the Synthesis of Organometallic Dendrimers" Organometallics, 2011, 30, 1920–1929.
• M. Herrero, J. Losada, M.P. García-Armada, B. Alonso, C.M. Casado, "Covalently cross-linked ferrocenyl PAMAMOS dendrimer networks." Australian Journal of Chemistry, 2011, 64, 147.

2006-2010

• A. Nievas, M. Medel, E. Hernández, E. Delgado, A. Martín, Avelino;  C. M. Casado, B. Alonso. "Redox-Active Heterometallic Ferrocenylalkynyl Carbosilane Dendrimers Incorporating Os3(CO)10 Clusters." Organometallics, 2010, 29,  4291–4297.
• Campos, Bruno B.; Algarra, Manuel; Alonso, Beatriz; Casado, Carmen M.; Esteves da Silva, Joaquim C. G.. "Mercury(ii) sensing based on the quenching of fluorescence of CdS-dendrimer nanocomposites." Analyst, 2009, 134, 2447-2452.
• R. Villoslada, B. Alonso, C.M. Casado, M.P. García-Armada, J. Losada. " Anion receptor electrochemical sensing properties of poly(propyleneimine)dendrimers with ferrocenylamidoalkyl terminal groups." Organometallics, 2009, 28, 727-733.
• M.P. García-Armada, J. Losada, F. J. López-Villanueva, H. Frey, B. Alonso, C.M. Casado. "Electrochemical and bioelectrocatalytical properties of novel block-copolymers containing interacting ferrocenyl units." Journal of Organometallic Chemistry, 2008, 693, 2803-2811.
• F.J. Martínez, B. González, B. Alonso, J. Losada, M.P. García-Armada, C.M. Casado. "Synthesis and Redox Properties of an Electropolymerizable Amido Ferrocenyl Pyrrole- Functionalized Dendrimer." Journal of Inorganic and Organometallic Polymers and Materials, 2008, 18, 51-58.
• M. Zamora, S. Herrero, J. Losada, I. Cuadrado, C. M. Casado, B. Alonso. “Synthesis and Electrochemistry of Octamethyl-Functionalized Dendrimers." Organometallics, 2007, 26, 2688- 2693.
• M. Zamora, B. Alonso, C. Pastor, I. Cuadrado. “Multiredox Heterometallic Carbosilane Dendrimers” Organometallics, 2007, 26, 5153-5164.
• B. Alonso, C. Álvarez-Toledano, E. Delgado, E. Hernández, I. García-Orozco, R. A. Toscano. “Triosmium Compounds Containing the Oxametalacycle [Os(CO)3{C(R)=CHC(O)CH=C(H)C5H4FeC5H5})] moiety. Synthesis and Electrochemical Studies." J. Organomet. Chem., 2007, 692, 5117-5124
• E. Delgado, E. Hernández, A. Nievas, M. Villa, A. Martín, B. Alonso.“Synthesis, Characterization and Reactivity studies of the New Compound [Os3(CO)9 (µ3-?2,?3,?3-{C5H5FeC5H3CCC(S)C(Fc)CHO})]." J. Organomet. Chem., 2007, 692, 5453-5458.
• B. Gómez-Lor, G. Hennrich, B. Alonso, A. Monge, E. Gutiérrez-Puebla, A. M. Echavarren."Redox-active C3-Symmetric Triindole based Triazacyclophane." Angew. Chem. Int. Ed., 2006, 45, 4491- 4494.
• B. Gómez-Lor, B. Alonso, A. Omenat, J. L. Serrano. “Electroactive C3 symmetric discotic liquid-crystalline triindoles." Chem. Commun., 2006, 5012-5014.
• E. Ramírez-Oliva, I. Cuadrado, C. M. Casado, J. Losada, B. Alonso. "Functionalization of Linear and Cyclic Siloxanes and a Dendritic Carbosilane whith (?5-C5H5)Fe(CO)2Si(CH3)2CH=CH2 via Hydrosilylation Reaction." J. Organomet. Chem., 2006, 691, 1131- 1137.
• M. P. García-Armada, J. Losada, M. Zamora, B. Alonso, I. Cuadrado, C. M. Casado. “Electrocatalytical Properties of Polymethylferrocenyl Dendrimers and their Applications in Biosensing.” Bioelectrochemistry, 2006, 69, 65- 73.
• J. Losada, M. Zamora, P. García Armada, I. Cuadrado, B. Alonso, C. M. Casado. "Bienzyme Sensors Based on Novel Polymethylferrocenyl Dendrimers." Anal. Bioanal. Chem., 2006, 385, 1209- 1217.
• B. González, B. Alonso, J. Losada, M. P. García-Armada, C. M. Casado “Aza-Crown Ethers Attached to Dendrimers through Amidoferrocenyl Units” Organometallics, 2006, 25, 3558- 3561.
• F. Lopez-Villanueva, A. Garcia Marcos, K. Fischer, M. Schmidt, B. Alonso, C.M. Casado, M.P. Garcia Armada, J. Losada, H. Frey. “Influence of block length for ferrocenyl-functionalized block copolymers as precursor for biosensoric applications.” Polymer Preprints, 2006, 47, 1087-1088.

2001-2005

• E. González-Cantalapiedra, M. Ruiz, B. Gómez-Lor, B. Alonso, D. García-Cuadrado, D. J. Cárdenas, A. M. Echavarren. "New Building blocks Based on Truxene Cores: Synthesis of Functionalized syn- Tri- and Hexasubstituted Derivatives."Eur. J. Org. Chem., 2005, 4127- 4140.
• J. Losada, M. P. García Armada, I. Cuadrado, B. Alonso, B. González, C. M. Casado, J. Zhang. "Ferrocenyl and Permethylferrocenyl Cyclic and Polyhedral Siloxane Polymers as Mediators in Amperometric Biosensors." J. Organomet. Chem., 2004, 689, 2799- 2807.
• P. García Armada, J. Losada, I. Cuadrado, B. Alonso, B. González, C. M. Casado, J. Zhang. "Preparation of Biosensors Based in a Siloxane Homopolymer with Interacting Ferrocenes for the Amperometric Detection of Peroxides." Sens. Actuat., B. Chem., 2004, 101, 143- 149.
• B. Alonso, P. García Armada, J. Losada, I. Cuadrado, B. González, C. M. Casado. "Amperometric Enzyme Electrodes for Aerobic and Anaerobic Glucose Monitoring Prepared by Glucose Oxidase Immobilized in Mixed Ferrocene-Cobaltocenium Dendrimers " Biosens. Bioelect., 2004, 19, 1617- 1625.
• B. Alonso, C. Castejón, E. Delgado, B. Donnadieu, E. Hernández. "Unexpected behaviour of the novel organometallic thioether C5H5FeC5H4C=CSC=CSiMe3 towards Ru3(CO)12." Organometallics, 2004, 23, 5115-5118.
• García Armada, P.; Losada, J.; Cuadrado, I.; Alonso, B.; González, B.; Ramírez-Oliva, E.; Casado, C.M. “Electrodes modified with a siloxane copolymer containing interacting ferrocenes for determination of hydrogen peroxide and glucose” Sensors and Actuators B. Chemical, 2003, 88, 190- 197.
• P. García Armada, J. Losada, I. Cuadrado, B. Alonso, B. González, C. M. Casado. “A siloxane Homopolymer with Interacting Ferrocenes as a New Material for the Preparation of Sensor Based on the Detection of Hydrogen Peroxide.” Electroanalysis, 2003, 15, 1109- 1114.
• I. Díaz, B. García, B. Alonso, C. M. Casado, M. Morán, J. Losada, J. Pérez-Pariente. "Ferrocenyl Dendrimers Incorporated into Mesoporous Silica: New Hybrid Redox-Active Materials" Chemistry of Materials, 2003, 15, 1073- 1079.
• B. Alonso, C. M. Casado, I. Cuadrado, M. Morán, A. E. Kaifer "Effective Recognition of H2PO4- by a New series of Dendrimers Functionalised with Ferrocenyl-Urea Termini." Chemical Communications, 2002, 1178.
• I. del Peso, B. Alonso, F. Lobete, C. M. Casado, I. Cuadrado, J. Losada. "A Polymerizable Pyrrole-Cobaltocenium Receptor for the Electrochemical Recognition of Anions in Solution and Immobilised onto Electrode Surfaces." Inorganic Chemistry Communications, 2002, 5, 288- 291.
• B. González, I. Cuadrado, B. Alonso, C. M. Casado, M. Morán, A. E. Kaifer "Mixed Cobaltocenium-Ferrocene Heterobimetallic Complexes and Their Binding Interactions with b-Cyclodextrin. A Three-State, Host-Guest System under Redox Control". Organometallics, 2002, 21, 3544- 3551.
• B. Alonso, J-C. Blais, D. Astruc. "Successive Activation and Perfunctionalization of Arenes by ?-Complexation to CpFe+ and Cp*Ru+ for the Construction of Organometallic Stars and Dendrimers." Organometallics, 2002, 21 (5), 1001-1003.
• B. Alonso, D. Astruc, J-C. Blais, S. Nlate, S. Rigaut, J. Ruiz, V. Sartor, C. Valerio. "Metallodendrimeres towards Enzyme Mimics and Molecular Electronics: New-Genertion Catalyst, Sensors and Molecular Batteries." Comptes Rendus Académie Sciences Paris, Chimie/Chemistry, 2001, 4, 173-180.
• I. Cuadrado, B. Alonso, C. M. Casado, B. González, B. García, E. Ramírez, M. Morán, J. Losada “Functionalization of linear and cyclic oligo siloxanes with ferrocenyl units electronically communicated via hydrosilylation reaction.” Journal of Organometallic Chemistry, 2001, 637-639, 642-652.
• K. Takada, D. J. Díaz, H. D. Abruña, I. Cuadrado, B. González, C. M. Casado, B. Alonso, M. Morán, J. Losada."Cobaltocenium-Functionalized Poly(propyleneimine) Dendrimers: Redox and Electromicrogravimetric Studies and AFM imaging." Chemistry. A European Journal, 2001, 7, 1109.

1996-2000

• B. González, I. Cuadrado, C. M. Casado, B. Alonso, C. J. Pastor."Reaction of Chlorocarbonyl Metallocenes of Iron and Cobalt with 1,4-Diaminobutane: Synthesis of a Heterobimetallic Ferrocene-Cobaltocenium Complex." Organometallics, 2000, 19, 5518-5521.
• C.M.Casado, B.González, I.Cuadrado, B.Alonso, M.Morán, J.Losada."Mixed Ferrocene-Cobaltocenium Dendrimers: The Most Stable Organometallic Redox Systems Combined in a Dendritic Molecule." Angewandte Chemie. International Ed. 2000, 39, 2135-2138.
• C. R. Arana, G. Chiericato Jr., C. Casado, I. Cuadrado, H. D. Abruña. "Electrocatalytic Reduction of Carbon Dioxide Mediated by Transition Metal Complexes with Terdentate Ligands Derived from di-Acetyl Pyridine." Inorganica Chimica Acta, 2000, 300-302, 32-42.
• I. Cuadrado, C. M. Casado, F. Lobete, B. Alonso, B. González, J. Losada, U. Amador" Preparation and Redox Properties of Novel Polymerizable Pyrrole- and Allyl-Functionalized Cobaltocenium Monomers and Siloxane-Based Cobaltocenium Polymers." Organometallics, 1999, 18, 4960-4969.
• Cuadrado, I.; Morán; M.; Casado, C. M.; Alonso, B.; Losada, J. "Organo-Transition Metal Dendritic Molecules." Coordination Chemistry Reviews, 1999, 193-195, 395-445.
• B. García, C. M. Casado, I. Cuadrado, B. Alonso, M. Morán, J. Losada"1,1’-Bis-(dimethylvinylsilyl) Ferrocene as Two-Directional Core for the Construction of Homo and Heterometallic Systems." Organometallics, 1999, 18, 2349-2356.
• H. A. Trujillo, C. M. Casado y D. Astruc. "Activation in Multiple Oxidation States: Comparison of Benzylic C-H Acidities and C-H Bond Dissociation Energies in the Isostructural 16-20-Electron Complexes [Fex(?5-C5R5)(?6-C5Me6)]n, x = 0-IV, R = H or Me; n = -1 to +3."Journal of the American Chemical Society 1999, 121, 5674-5686.
• Casado, C. M.; Cuadrado, I.; Alonso, B.; Morán; M.; Losada, J. "Silicon-based ferrocenyl dendrimers as anion receptors in solution and immobilized onto electrode surfaces."Journal of Electroanalytical Chemistry, 1999, 463, 87-92.
• Casado, C. M.; Cuadrado, I.; Morán; M.; Alonso, B.; García, B.; González, B.; Losada, J. "Redox-Active Ferrocenyl Dendrimers and Polymers in Solution and Immobilised on Electrode Surfaces." Coordination Chemistry Reviews, 1999, 185-186, 53-79.
• Casado, C. M.; Cuadrado, I.; Morán; M.; Alonso, B.; Barranco, M.; Losada, J. Cyclic siloxanes and Silsesquioxanes as Cores and Frameworks for the Construction of Ferrocenyl Dendrimers and Polymers."Applied Organometallic Chemistry, 1999, 13, 245-259.
• González, B.; Casado, C. M.; Alonso, B.; Cuadrado, I.; Morán; M.; Wang, Y.; Kaifer, A. E. "Synthesis, Electrochemistry and Cyclodextrin Binding of Novel Cobaltocenium-Functionalized Dendrimers." Chemical Communications, 1998, 2569-2570.
• Takada, K.; Díaz, D. J.; Abruña, H.; Cuadrado, I.; Casado, C.; Alonso, B.; Morán, M.; Losada, J. "Redox-Active Ferrocenyl Dendrimers: Thermodynamics and Kinetics of Adsorption, In-Situ EQCM Study of Redox Process and Tapping Mode AFM Imaging." Journal of the American Chemical Society, 1997, 119, 10763-10773.
• I. Cuadrado, C. M. Casado, B. Alonso, M. Morán, J. Losada, V. Belsky. "Dendrimers containing Organometallic Moieties electronically communicated."Journal of the American Chemical Society, 1997, 119, 7613-7614.
• R. Castro, I. Cuadrado, B. Alonso, C. M. Casado, M. Morán, A. Kaifer. "Multisite Inclusion Complexation of Redox Active Dendrimer Guests.” Journal of the American Chemical Society, 1997, 119, 5760-5761.
• J. Losada, I. Cuadrado, M. Morán, C. M. Casado, B. Alonso, M. Barranco. "Ferrocenyl silicon-based dendrimers as mediators in amperometric biosensors"Analytica Chimica Acta., 1997, 338, 191-198.
• I. Cuadrado, M. Morán, C. M. Casado, B. Alonso, F. Lobete, B. García, M. Ibisate, J. Losada. "Ferrocenyl Functionalized Poly(propylene imine) Dendrimers "Organometallics, 1996, 15, 5278-5280.
• I. Cuadrado, M. Morán, A. Moya, C. M. Casado, M. Barranco, B. Alonso. "Organometallic silicon-based dendrimers with peripheral Si-cyclopentadienyl, Si-Co and Si-Fe ?-bonds"Inorganica Chimica Acta., 1996, 251, 5-7.
• F. Lobete, I. Cuadrado, C. M. Casado, B. Alonso, M. Morán y J. Losada. "Silicon-Based Organometallic Dendritic Macromolecules Containing {?6-(Organosilyl)arene}Chromium Tricarbonyl Moieties"Journal of Organometallic Chemistry, 1996, 509, 109-113.

1991-1995

• C. M. Casado, T. Wagner y D. Astruc."Deprotonation of the Complexes [Ru(arene)Cp]+PF6- (arene = C6Me6 and fluorene): X-ray Crystal Structure of [Ru(?5-C6Me5CH2)-Cp] and Determination of the pKa Values Using the Iron Analogues" Journal of Organometallic Chemistry, 1995, 502, 143-145.
• B. Alonso, M. Morán, C. M. Casado, F. Lobete, J. Losada, I. Cuadrado. "Electrodes Modified with Electroactive Films of Organometallic Dendrimers"Chemistry of Materials, 1995, 7, 1440-1442.
• C. M. Casado, I. Cuadrado, M. Morán, B. Alonso, F. Lobete, J. Losada. "Synthesis of the First Redox-Active Organometallic Polymers Containing Cyclosiloxanes as Frameworks" Organometallics, 1995, 14, 2618-2620.
• C. M. Casado, M. Morán, J.Losada y I. Cuadrado. "Siloxane and Organosilicon Dimers, Monomers and Polymers with Amide Linked Ferrocenyl Moieties. Synthesis, Characterization and Redox Properties"Inorganic Chemistry, 1995, 34, 1668-1680.
• H. A. Trujillo, C. M. Casado y D. Astruc. "Thermodynamics of Benzylic C-H Activation in 18- and 19-Electron Iron Sandwich Complexes: Determination of pKa Values and Bond Dissociation Energies."Journal of the Chemical Society, Chemical Communications, 1995, 7-8.
• B. Alonso, I. Cuadrado, M. Morán, y J. Losada. "Organometallic Silicon Dendrimers." Journal of the Chemical Society, Chemical Communications, 1994, 2575-2576.
• M. Morán, C. M. Casado, I. Cuadrado, y J. Losada. "Ferrocenyl Substituted Octakis(dimethylsiloxy)octasilsesquioxanes: A New Class of Supramolecular Organometallic Compounds. Synthesis Characterization and Electrochemistry" Organometallics, 1993, 12, 4327-4333.
• M. Morán, I. Cuadrado, C. Pascual, C. M. Casado y J. Losada. "{?6-(Organosilyl)arene}chromium Tricarbonyl Complexes: Synthesis Characterization and Electrochemistry" Organometallics, 1992, 11, 1210-1220.
• M. Morán, C. M. Casado, I. Cuadrado y J. Losada "{?6- Phenylmethylsila-14-crown-5}Chromium Tricarbonyl. Synthesis, Characterization and Electrochemical Studies on the first Example of an Electroactive Ionophore Containing a Silacrown." Inorganica Chimica Acta, 1991, 185, 33-37.

Capítulos de libro

• I. Cuadrado, M. Morán, J. Losada, C. M. Casado, C. Pascual, B. Alonso, F. Lobete. "Organometallic Dendritic Macromolecules: Organosilicon and Organometallic Entities as Cores or Building Blocks" en Advances in Dendritic Macromolecules Vol. 3 1996, pp. 152-193. JAI PRESS. ISBN: 0-7623-0069-8
• B. Alonso, E. Alonso, D. Astruc, J-C. Blais, L. Djakovitch, J. L. Fillaut, S. Nlate, F. Moulines, S. Rigaut, J. Ruiz, C. Valerio. "Dendrimers Containing Ferrocenyl- or Other Transition-Metal Sandwich Groups " en Advances in Dendritic Macromolecules Vol. 5 2002, pp. 89-127. JAI PRESS. ISBN: 0-7623-0839-7
• C. M. Casado, B. Alonso, J. Losada y M. P. García-Armada "Redox-Active Organometallic Dendrimers as Electrochemical Sensors." en  Designing Dendrimers, S. Campagna, P. Ceroni, and F. Puntoriero (ed.),  John Wiley & Sons, Hoboken, NJ, en prensa.