Grupos de investigación - Product and Process Design based on Ionic Liquids / Diseño de Producto y Proceso basados en Líquidos Iónicos

Líquidos iónicos; Captura y utilización de CO2; Operaciones avanzadas de separación; Procesos sostenibles

Publicaciones más relevantes

1. J. Palomar, J. Lemus, P. Navarro, C. Moya, R. Santiago, D. Hospital, E. Hernández. Process simulation and optimization on ionic liquids (2024) Chemical Reviews, 124 (4), pp. 1649 ¿ 1737. 2. Dorado-Alfaro, S., Hospital-Benito, D., Moya, C., Navarro, P., Lemus, J., Palomar, J. Exploiting process thermodynamics in carbon capture from direct air to industrial sources: The paradigmatic case of ionic liquids (2024) Carbon Capture Science and Technology, 13, 100320 3. Hospital-Benito, D., El-Bijou, R., Dufour, J., Palomar, J. Techno-economic assessment of bio-hythane upgrading processes based on ionic liquids (2024) Chemical Engineering Journal, 497, 154889 4. Belinchón, A., Hernández, E., Navarro, P., Palomar, J. A step closer to sustainable CO2 conversion: Limonene carbonate production driven by ionic liquids (2024) Journal of Cleaner Production, 460, art. no. 142587. 5. Belinchón, A., Pereira, A., Hernández, E., Navarro, P., Palomar, J. Extending the application of bifunctional ionic liquid-based integrated capture and conversion of CO2 to produce cyclic carbonates (2024) Journal of CO2 Utilization, 85, art. no. 102886. 6. Hernández, E., Navarro, P., Pescarmona, P., Palomar, J. Dissociation role on the catalytic activity of organic halides in CO2 conversion to cyclic carbonates: Experimental and computational study (2024) Journal of CO2 Utilization, 88, art. no. 102929. 7. Mild one-pot production of glycerol carbonate from CO2 with separation from ionic liquid catalyst (2024) Separation and Purification Technology, 356, art. no. 129970. 8. Navarro, P., Moreno, D., Larriba, M., García, J., Rodríguez, F., Canales, R., Palomar, J. An overview process analysis of the aromatic-aliphatic separation by liquid-liquid extraction with ionic liquids (2023) Separation and Purification Technology, art. no. 123848. 9. Hospital-Benito, D., Moya, C., Gazzani, M., Palomar, J.Direct air capture based on ionic liquids: From molecular design to process assessment (2023) Chemical Engineering Journal, 468, 143630 10. Arroyo-Avirama, A.F., Carreño-Guzmán, S., Lorenzo-Llanes, J., Palomar, J., Canales, R.I.In Situ Product Recovery of ß-Ionone from a Fermentation Broth: Computational Solvent Selection and Process Design of Its Extraction and Purification (2023) ACS Sustainable Chemistry and Engineering, 11(24), pp. 9065¿9076 11. Hospital-Benito, D., Díaz, I., Palomar, J. Technical performance and environmental assessment of an ionic liquid-based CCS process for hydrogen production (2023) Sustainable Production and Consumption, 38, pp. 283¿294 12. Ayuso, M., Mateo, S., Belinchón, A., Navarro, P., Palomar, J., García, J., Rodríguez, F. Cyclic carbonates as solvents in the dearomatization of refinery streams: experimental liquid-liquid equilibria, modelling, and simulation (2023) Journal of Molecular Liquids, 380, art. no. 121710. 13. Hernández, E., Belinchón, A., Santiago, R., Moya, C., Navarro, P., Palomar, J. Solvent-catalyst optimization of ionic liquid-based CO2 conversion to propylene carbonate: Laboratory validation and techno-economic analysis (2023) Journal of CO2 Utilization, 69, art. no. 102417. 14. Rodríguez-Llorente, D., Martín-Gutiérrez, D., Suárez-Rodríguez, P., Navarro, P., Álvarez-Torrellas, S., García, J., Larriba, M. Sustainable recovery of phenolic antioxidants from real olive vegetation water with natural hydrophobic eutectic solvents and terpenoids (2023) Environmental Research, 220, art. no. 115207. 15. Lemus, J., Paramio, C., Hospital-Benito, D., Santiago, R., Palomar, J.Selective CO2/CH4Separation by Fixed-Bed Technology Using Encapsulated Ionic Liquids (2022) ACS Sustainable Chemistry and Engineering, 10(42), pp. 13917¿13926 16. Arevalo-Bastante, A., Omar, S., Palomar, J., Rodriguez, J.J., Gómez-Sainero, L.M. Design of hydrodechlorination catalysts on the basis of chloromethanes-metallic active sites interactions (2022) Chemical Engineering Journal, 446, 136893 17. Hospital-Benito, D., Lemus, J., Moya, C., ... Paramio, C., Palomar, J.Aspen plus supported design of pre-combustion CO2 capture processes based on ionic liquids (2022) Separation and Purification Technology, 290, 120841 18. Hospital-Benito, D., Lemus, J., Moya, C., Santiago, R., Palomar, J.Improvement of CO2 capture processes by tailoring the reaction enthalpy of Aprotic N¿Heterocyclic anion-based ionic liquids (2022) Chemical Engineering Journal Advances, 10, 100291 19. Sosa, J.E., Santiago, R., Redondo, A.E., Palomar, J., Pereiro, A.B.Design of Ionic Liquids for Fluorinated Gas Absorption: COSMO-RS Selection and Solubility Experiments (2022) Environmental Science and Technology, 56(9), pp. 5898¿5909 20. Moya, C., Santiago, R., Hospital-Benito, D., Lemus, J., Palomar, J.Design of biogas upgrading processes based on ionic liquids (2022) Chemical Engineering Journal, 428, 132103 21. Rodríguez-Llorente, D., Hernández, E., Gutiérrez-Sánchez, P., Navarro, P., Ismael Águeda, V., Álvarez-Torrellas, S., García, J., Larriba, M. Extraction of pharmaceuticals from hospital wastewater with eutectic solvents and terpenoids: Computational, experimental, and simulation studies (2023) Chemical Engineering Journal, 451, art. no. 138544. 22. Hernández, E., Belinchón, A., Pachón, E.R., Navarro, P., Palomar, J. Toward Sustainable and Cost-Effective CO2 Conversion Processes to Propylene Carbonate Based on Ionic Liquids (2022) Advanced Sustainable Systems, 6 (12), art. no. 2200384. 23. Gutiérrez-Sánchez, P., Navarro, P., Álvarez-Torrellas, S., García, J., Larriba, M. Extraction of neonicotinoid pesticides from aquatic environmental matrices with sustainable terpenoids and eutectic solvents (2022) Separation and Purification Technology, 302, art. no. 122148. 24. Hernández, E., Hospital-Benito, D., Moya, C., Ortiz, R., Belinchón, A., Paramio, C., Lemus, J., Navarro, P., Palomar, J. Integrated carbon capture and utilization based on bifunctional ionic liquids to save energy and emissions (2022) Chemical Engineering Journal, 446, art. no. 137166. 25. Belinchón, A., Santiago, R., Hernández, E., Moya, C., Navarro, P., Palomar, J. Reaction-extraction platforms towards CO2-derived cyclic carbonates catalyzed by ionic liquids (2022) Journal of Cleaner Production, 368, art. no. 133189. 26. Santiago, R., Díaz, I., González-Miquel, M., Navarro, P., Palomar, J. Assessment of bio-ionic liquids as promising solvents in industrial separation processes: Computational screening using COSMO-RS method (2022) Fluid Phase Equilibria, 560, art. no. 113495. 27. Hernández, E., Santiago, R., Belinchón, A., Maria Vaquerizo, G., Moya, C., Navarro, P., Palomar, J. Universal and low energy-demanding platform to produce propylene carbonate from CO2 using hydrophilic ionic liquids (2022) Separation and Purification Technology, 295, art. no. 121273. 28. Navarro, P., Hernández, E., Rodríguez-Llorente, D., Maldonado-López, I., Santiago, R., Moya, C., Belinchón, A., Larriba, M., Palomar, J. Fine-tune simultaneous dearomatization, desulfurization and denitrogenation of liquid fuels with CO2-derived cyclic carbonates (2022) Fuel, 321, art. no. 124005. 29. Belinchón, A., Hernández, E., Vázquez, J., Santiago, R., Moya, C., Larriba, M., Navarro, P., Palomar, J. Biocarbonates Derived from CO2and Terpenes: Molecular Design for Aqueous Mixture Treatment Driven by COSMO-RS (2022) ACS Sustainable Chemistry and Engineering, 10 (29), pp. 9635-9643. 30. Ayuso, M., Navarro, P., Moya, C., Moreno, D., Palomar, J., García, J., Rodríguez, F. Extractive Distillation with Ionic Liquids To Separate Benzene, Toluene, and Xylene from Pyrolysis Gasoline: Process Design and Techno-Economic Comparison with the Morphylane Process (2022) Industrial and Engineering Chemistry Research, 61 (6), pp. 2511-2523. 31. Gutiérrez-Sánchez, P., Rodríguez-Llorente, D., Navarro, P., Águeda, V.I., Álvarez-Torrellas, S., García, J., Larriba, M. Extraction of antibiotics identified in the EU Watch List 2020 from hospital wastewater using hydrophobic eutectic solvents and terpenoids (2022) Separation and Purification Technology, 282, art. no. 120117. 32. Vadillo, J.M., Hospital-Benito, D., Moya, C., Garea, A., Irabien, A. Modelling and simulation of hollow fiber membrane vacuum regeneration for CO2 desorption processes using ionic liquids (2021) Separation and Purification Technology, 2021, 277, 119465 33. Dai, C., Qi, Z., Lei, Z., Palomar, J.COSMO-based models (2021) Green Energy and Environment, 6(3), pp. 309¿310 34. Gouveia, A.S.L., Yáñez, M., Alves, V.D., ... Tomé, L.C., Marrucho, I.M.CO2/H2 separation through poly(ionic liquid)¿ionic liquid membranes: The effect of multicomponent gas mixtures, temperature and gas feed pressure (2021) Separation and Purification Technology, 259, 118113 35. Hospital-Benito, D., Lemus, J., Moya, C., Ferro, V.R., Palomar, J. Techno-economic feasibility of ionic liquids-based CO2 chemical capture processes (2021) Chemical Engineering Journal, 407, 127196 36. Lemus, J., Santiago, R., Hospital-Benito, D., ... Hallett, J.P., Palomar, J.Process Analysis of Ionic Liquid-Based Blends as H2S Absorbents: Search for Thermodynamic/Kinetic Synergies (2021) ACS Sustainable Chemistry and Engineering, 9(5), pp. 2080¿2088 37. Santiago, R., Hernández, E., Moya, C., Vela, S., Navarro, P., Palomar, J. Fatty alcohol/water reaction-separation platform to produce propylene carbonate from captured CO2 using a hydrophobic ionic liquid (2021) Separation and Purification Technology, 275, art. no. 119143. 38. Santiago, R., Moya, C., Hernández, E., Cojocaru, A.-V., Navarro, P., Palomar, J. Extending the ability of cyclic carbonates for extracting BTEX to challenging low aromatic content naphtha: the designer solvent role at process scale (2021) Computers and Chemical Engineering, 154, art. no. 107468. 39. Rodríguez-Llorente, D., Navarro, P., Santiago, R., Águeda, V.I., Álvarez-Torrellas, S., García, J., Larriba, M. Extractive removal and recovery of bisphenol A from aqueous solutions using terpenoids and hydrophobic eutectic solvents (2021) Journal of Environmental Chemical Engineering, 9 (5), art. no. 106128. 40. Hernández, E., Santiago, R., Moya, C., Vela, S., Navarro, P., Palomar, J. Close-cycle process to produce CO2-derived propylene carbonate based on amino acid catalyst and water (2021) Journal of CO2 Utilization, 52, art. no. 101656. 41. Cañada-Barcala, A., Rodríguez-Llorente, D., López, L., Navarro, P., Hernández, E., Águeda, V.I., Álvarez-Torrellas, S., Parajó, J.C., Rivas, S., Larriba, M. Sustainable Production of Furfural in Biphasic Reactors Using Terpenoids and Hydrophobic Eutectic Solvents (2021) ACS Sustainable Chemistry and Engineering, 9 (30), pp. 10266-10275. 42. Ayuso, M., Ovejero-Pérez, A., Delgado-Mellado, N., Navarro, P., Larriba, M., García, J., Rodríguez, F. Tetrathiocyanatocobaltate and bis(trifluoromethylsulfonyl)imide-based ionic liquids as mass agents in the separation of cyclohexane and cyclohexene mixtures by homogeneous extractive distillation (2021) Journal of Chemical Thermodynamics, 157, art. no. 106403. 43. Hernández, E., Santiago, R., Moya, C., Navarro, P., Palomar, J. Understanding the CO2 valorization to propylene carbonate catalyzed by 1-butyl-3-methylimidazolium amino acid ionic liquids (2021) Journal of Molecular Liquids, 324, art. no. 114782. 44. Hernández, E., Santiago, R., Moya, C., Navarro, P., Palomar, J. Multiscale evaluation of CO2-derived cyclic carbonates to separate hydrocarbons: Drafting new competitive processes (2021) Fuel Processing Technology, 212, art. no. 106639. 45. Rodríguez-Llorente, D., Cañada-Barcala, A., Muñoz, C., Pascual-Muñoz, G., Navarro, P., Santiago, R., Águeda, V.I., Álvarez-Torrellas, S., García, J., Larriba, M. Separation of phenols from aqueous streams using terpenoids and hydrophobic eutectic solvents (2020) Separation and Purification Technology, 251, art. no. 117379. 46. Moya, C., Hospital-Benito, D., Santiago, R., Lemus, J., Palomar, J. Prediction of CO2 chemical absorption isotherms for ionic liquid design by DFT/COSMO-RS calculations (2020) Chemical Engineering Journal Advances, 4, 100038 47. Fernández-Stefanuto, V., Esteiro, P., Santiago, R., ... Palomar, J., Tojo, E.Design and synthesis of alverine-based ionic liquids to improve drug water solubility (2020) New Journal of Chemistry, 44(46), pp. 20428¿20433 48. Santiago, R., Moya, C., Palomar, J.Siloxanes capture by ionic liquids: Solvent selection and process evaluation (2020) Chemical Engineering Journal, 401, 126078 49. Igual Muñoz, A., Alonso-Morales, N., Palomar, J., Gilarranz, M.A., Mischler, S.Tribological properties of gold matrix composite coatings with carbon nanocapsules containing ionic liquid lubricants (2020) Materials Letters, 279, 128501 50. Campos-Franzani, M.I., Gajardo-Parra, N.F., Pazo-Carballo, C., Escalona, N., Canales, R.I.Extraction of guaiacol from hydrocarbons as an alternative for the upgraded bio-oil purification: Experimental and computational thermodynamic study (2020) Fuel, 280, 118405 51. Sosa, A., Ortega, J., Fernández, L., Palomar, J.Development of a method to model the mixing energy of solutions using COSMO molecular descriptors linked with a semi-empirical model using a combined ANN-QSPR methodology (2020) Chemical Engineering Science, 224, 115764 52. Sosa, J.E., Santiago, R., Hospital-Benito, D., ... Pereiro, A.B., Palomar, J.Process Evaluation of Fluorinated Ionic Liquids as F-Gas Absorbents (2020) Environmental Science and Technology, 54(19), pp. 12784¿12794 53. Silva, L.P., Moya, C., Sousa, M., ... Coutinho, J.A.P., Carvalho, P.J.Encapsulated Amino-Acid-Based Ionic Liquids for CO2 Capture (2020) European Journal of Inorganic Chemistry, 33, pp. 3158¿3166 54. Hospital-Benito, D., Lemus, J., Moya, C., Santiago, R., Palomar, J.Process analysis overview of ionic liquids on CO2 chemical capture (2020) Chemical Engineering Journal, 390, 124509 55. Santiago, R., Lemus, J., Outomuro, A.X., Bedia, J., Palomar, J.Assessment of ionic liquids as H2S physical absorbents by thermodynamic and kinetic analysis based on process simulation (2020) Separation and Purification Technology, 233, 116050 56. Mena, I.F., Diaz, E., Palomar, J., Rodriguez, J.J., Mohedano, A.F.Cation and anion effect on the biodegradability and toxicity of imidazolium¿ and choline¿based ionic liquids (2020) Chemosphere, 240, 124947 57. Hospital-Benito, D., Lemus, J., Santiago, R., Palomar, J.Thermodynamic and kinetic evaluation of ionic liquids + tetraglyme mixtures on CO2 capture (2020) Journal of CO2 Utilization, 35, pp. 185¿193 58. Navarro, P., Palma, A.M., García, J., Rodríguez, F., Coutinho, J.A.P., Carvalho, P.J. High pressure density of tricyanomethanide-based ionic liquids: Experimental and PC-SAFT modelling (2020) Fluid Phase Equilibria, 520, art. no. 112652. 59. Ayuso, M., Palma, A.M., Larriba, M., Delgado-Mellado, N., García, J., Rodríguez, F., Coutinho, J.A.P., Carvalho, P.J., Navarro, P. Experimental and CPA EoS description of the key components in the BTX separation from gasolines by extractive distillation with tricyanomethanide-based ionic liquids (2020) Industrial and Engineering Chemistry Research, 59 (33), pp. 15058-15068. 60. Ayuso, M., Cañada-Barcala, A., Larriba, M., Navarro, P., Delgado-Mellado, N., García, J., Rodríguez, F. Enhanced separation of benzene and cyclohexane by homogeneous extractive distillation using ionic liquids as entrainers (2020) Separation and Purification Technology, 240, art. no. 116583. 61. Ayuso, M., Navarro, P., Palma, A.M., Larriba, M., Delgado-Mellado, N., García, J., Rodríguez, F., Coutinho, J.A.P., Carvalho, P.J. Separation of benzene from methylcycloalkanes by extractive distillation with cyano-based ionic liquids: Experimental and CPA EoS modelling (2020) Separation and Purification Technology, 234, art. no. 116128.

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